Product ID:CCH DRY CHLORINATOR GRANULAR
MSDS Date:02/13/1989
FSC:6810
NIIN:01-183-7712
MSDS Number: BMZZZ

OLIN CORPORATION

120-LONG RIDGE ROAD
STAMFORD, CT 06904-1355
US

Emergency Phone: 800-654-6911

Info Phone: 203-789-5436

Cage: 99530

OLIN CORPORATION

4500 NORWALK, CT 06856-4500 US

Telephone: 203-750-3000/800-511-MSDS

Cage: 99530

CALCIUM HYPOCHLORITE

CAS: 22464-76-2

RTECS: NH3485500

Fraction By Weight: 65-75%

SODIUM CHLORIDE

CAS: 7647-14-5

RTECS: VZ4725000

Fraction By Weight: 10-20%

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 5.5-10%

CALCIUM CHLORATE

CAS: 10137-74-3

RTECS: FN9800000

Fraction By Weight: 0-5%

CALCIUM CHLORIDE

CAS: 10043-52-4

RTECS: EV9800000

Fraction By Weight: 0-5%

CALCIUM HYDROXIDE

CAS: 1305-62-0

RTECS: EW2800000

Fraction By Weight: 0-4%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 5 MG/M3; 9293

CALCIUM CARBONATE

CAS: 471-34-1

RTECS: FF9335000

Fraction By Weight: 0-4%

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 850 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:THIS MATERIAL HAS THE POTENTIAL TO BE
IMMEDIATELY DANGEROUS TO LIFE AND HEALTH. IRRITATING TO THE NOSE,
MOUTH, THROAT, AND LUNGS. CAN BURN RESPIRATORY TRACT. HIGH
CONCENTRATIONS OR CHRONIC SMALLER EXP OSURES CAN RESULT IN
PERMANENT LUNG DAMAGE. EXPOSURE TO EYE AND SKIN CAUSES SEVERE
IRRITATION AND CAN RESULT IN DAMAGE.
Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS
LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:SEVERE IRRITATION AND BURNING TO EXPOSED TISSUE
OF EYES, SKIN, RESPIRATORY TRACT. INGESTION CAN BURN THE ENTIRE
GASTROINTESTINAL TRACT INCLUDING THE STOMACH AND INTESTINES,
RESULTING IN VOMITING, DIAR RHEA, BLEEDING AND/OR TISSUE
ULCERATION. CAUSES SCAR TISSUE FORMATION.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF SKIN,
CARDIOVASCULAR AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK
FROM EXPOSURE.

First Aid:EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:WASH WITH SOAP
& WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE.
INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING IF NECESSARY.
INGESTED:DO N OT INDUCE VOMITING. GIVE 2 LARGE GLASSES OF MILK OR
WATER AND GET IMMEDIATE MEDICAL CARE. DOCTOR TO ORDER VOMITING.
NOTHING BY MOUTH IF UNCONSCIOUS. IF IRRITATION PERSISTS OR IS
SEVERE,SEE A DOCTOR.

Flash Point:NON-FLAMMABLE
Extinguishing Media:PRODUCT IS NON FLAMMABLE. EXTINGUISH FIRE WITH
MEDIA APPROPRIATE FOR SOURCE OF FIRE. DO NOT USE AMMONIUM
COMPOUNDS.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. DO NOT USE FIRE
EXTINGUISHERS CONTAINING AMMONIUM COMPOUNDS. SEE OTHER PRECAUT.

Spill Release Procedures:USE APPROPRIATE SAFETY EQUIPMENT. PICK UP
SPILLED MATERIAL AND PLACE IN CLEAN, DRY CONTAINER FOR DISPOSAL. IF
SPILLED INTO WATER, MONITOR FOR AVAILABLE CHLORINE AND PH. STAY
UPWIND OF SPILLS, IF POSSI BLE.
Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY SUPPLIER

Handling and Storage Precautions:STORE IN A COOL (BELOW 125F), DRY,
WELL VENTILATED AREA. KEEP CONTAINER CLOSED WHEN NOT IN USE.
PROTECT FROM PHYSICAL DA
Other Precautions:MATERIAL IS A STRONG OXIDIZER. IN CONTACT WITH
ORGANIC COMPOUNDS, ESPECIALLY LIQUIDS IT MAY CAUSE COMBUSTION,
FIRES AND POSSIBLE EXPLOSIONS.

Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE
NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR OR RESPIRATOR FOR DUST
AND/OR CHLORINE IF EXPOSURE IS ABOVE THE TLV/PEL. SEE 29 CFR
1910.134 FOR REGULATIONS PERTAINING TO RESPIRATOR USE.
Ventilation:USE LOCAL EXHAUST TO MINIMIZE DUST AND CHLORINE LEVELS.
Protective Gloves:NEOPRENE OR PVC
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. IMPERVIOUS WORK
CLOTHING AND APRON AS REQUIRED TO AVOID SKIN AND EYE CONTACT.
Work Hygienic Practices:DO NOT TAKE INTERNALLY. AVOID CONTACT WITH EYES
SKIN OR CLOTHING.IF CONTACTED WASH OFF WITH WATER.
Supplemental Safety and Health
MSDS RECEIVED FROM NAVY (FOCAL POINT N). NAVY IDENTIFIED NSN. PH OF A
1% SOLUTION = 11.

HCC:D1
Decomp Temp:Decomp Text:350F,177C
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE, FREE FLOWING POWDER, CHLORINE-LIKE ODOR.

Stability Indicator/Materials to Avoid:YES
ACIDS, ORGANICS, NITROGEN-CONTAINING COMPOUNDS, DRY POWDER FIRE
EXTINGUISHERS, CORROSIVE OR FLAMMABLE MATERIALS.
Stability Condition to Avoid:HIGH TEMPERATURES (>125F), SPARKS, AND
OPEN FLAMES
Hazardous Decomposition Products:CHLORINE GAS

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS. CONTAMINATED SPILL MATERIAL
MAY BE A HAZARDOUS WASTE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.